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This book provides a comprehensive and systematic exploration of piezoelectric and ferroelectric materials, bridging the gap between fundamental physical theories and advanced materials engineering. Beginning with the foundational principles of piezoelectricity and ferroelectricity, the text elucidates key phenomena such as polarization mechanisms, hysteresis, and structural phase transitions. It deeply investigates the perovskite structural family, with a specific focus on the lead zirconate titanate (PZT) solid solution and its behavior near the Morphotropic Phase Boundary (MPB). Furthermore, the book explores the critical role of chemical modifications, particularly rare-earth doping strategies, such as the incorporation of Samarium in tailoring the dielectric and electromechanical properties of these functional ceramics.
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